TY - JOUR T1 - Silicone Wristband Passive Samplers Yield Highly Individualized Pesticide Residue Exposure Profiles. JF - Environ Sci Technol Y1 - 2018 A1 - Raf Aerts A1 - Laure Joly A1 - Philippe Szternfeld A1 - Khariklia Tsilikas A1 - Koen De Cremer A1 - Philippe Castelain A1 - Jean-Marie Aerts A1 - Jos Van Orshoven A1 - Ben Somers A1 - Marijke Hendrickx A1 - Mirjana Andjelkovic A1 - An Van Nieuwenhuyse KW - Dietary exposure KW - environmental exposure KW - LC-MS/MS KW - passive sampler KW - Pesticide residues KW - wristband sampler AB -

Monitoring human exposure to pesticides and pesticide residues (PRs) remains crucial for informing public health policies, despite strict regulation of plant protection product and biocide use. We used 72 low-cost silicone wristbands as noninvasive passive samplers to assess cumulative 5-day exposure of 30 individuals to polar PRs. Ethyl acetate extraction and LC-MS/MS analysis were used for the identification of PRs. Thirty-one PRs were detected of which 15 PRs (48%) were detected only in worn wristbands, not in environmental controls. The PRs included 16 fungicides (52%), 8 insecticides (26%), 2 herbicides (6%), 3 pesticide derivatives (10%), 1 insect repellent (3%), and 1 pesticide synergist (3%). Five detected pesticides were not approved for plant protection use in the EU. Smoking and dietary habits that favor vegetable consumption were associated with higher numbers and higher cumulative concentrations of PRs in wristbands. Wristbands featured unique PR combinations. Our results suggest both environment and diet contributed to PR exposure in our study group. Silicone wristbands could serve as sensitive passive samplers to screen population-wide cumulative dietary and environmental exposure to authorized, unauthorized and banned pesticides.

VL - 52 CP - 1 M3 - 10.1021/acs.est.7b05039 ER -